It could be a corrupted legendary Pokemon. This Pokemon was once good but something happened that turned it evil. It sees Ash's growing power and connection to the other legendaries as a threat. It tries to undermine Ash at every turn, using its own powers and minions (maybe other Pokemon it has corrupted) to stop Ash from fulfilling his destiny as the chosen one.
Team Rocket could still be the main antagonists. Even though they usually have comical failures, in this fanfiction, they could discover Ash's connection to the legendary Pokemon and try to use it for their own evil plans. Maybe they want to capture the legendary Pokemon through Ash or steal the power that Ash has because of his chosen - one status.
It could be Team Rocket. They are always after rare and powerful pokemon. In this fanfiction, they might have a new and devious plan to steal the legendary pokemon that Ash is trying to catch. Their comical yet persistent attempts to thwart Ash would add an interesting dynamic to the story.
Perhaps an ancient evil spirit that was sealed away long ago. The hatching of the legendary starter's egg is a sign that the spirit can break free. It wants to possess the starter to regain its full power and take over the Pokemon world. This would make for a very dark and menacing antagonist, and Ash would have to use all his skills and the power of his friendship to defeat it.
Obviously, Ash is one of the main characters. Since it's about him being a legendary Pokemon in this fanfiction, he's central to the story.
Ash as the Chosen One in Pokemon fanfiction is a really interesting concept. It gives a whole new layer to his character. He could be given a special Pokemon by some mysterious force that is crucial for his destiny. This Pokemon might be one that no one has ever seen before. His friends would also play different roles, perhaps as protectors or guides to help him fulfill his chosen - one duties. And his battles would become even more epic as he has this greater responsibility on his shoulders.
Maybe a powerful and evil pokemon trainer who has a vendetta against Ash. Now that Ash is in a vulnerable pokemon form, this trainer could try to capture and control him. The trainer might have some dark motives related to using Ash's unique situation to gain power in the pokemon world.
It could be a powerful and evil Pokemon trainer who wants to capture Ash in his new Pokemon form. This trainer might be after Ash because he believes that a human - turned - Pokemon has some special power or value.
A third plot idea might be that Ash is the chosen one to bring peace between the different factions of legendary Pokemon. There could be some legendary Pokemon that are at odds with each other, and Ash, with his unique bond with Pokemon in general, is the only one who can bridge the gap. He would have to understand the reasons for their conflicts, which could be rooted in ancient history or disputes over territory. Along the way, he'd have to convince both sides that cooperation is better than conflict, and he might use his own experiences with his Pikachu and other Pokemon friends to show them how different species can get along.
Ash is definitely one of the main characters since it's about him being the chosen one. His Pokémon partners like Pikachu are also likely to be main characters as they would be involved in his journey as the chosen one.
Obviously, Ash is one of the main characters. He's the protagonist who has a passion for pokemon and is always eager to become a pokemon master. And the legendary pokemon he encounters or befriends would also be important characters. For instance, if it's Lugia, Lugia would play a major role in the story as it's a very powerful and mysterious pokemon.
The appeal lies in seeing Ash in new and exciting situations. With legendaries involved, his journey becomes more epic. It's like taking the underdog story of Ash in the anime and supercharging it.