In fanfiction, Luffy's character in Gear 5 might develop a greater sense of responsibility. Since Gear 5 is so powerful, he realizes he has to be more careful about using it. For example, he might avoid using it in areas where there are a lot of innocent bystanders.
Luffy uses Gear 5 in a significant battle towards the later part of the manga. But the exact chapter or arc can vary depending on how you're reading it.
In some One Piece Luffy Gear 5 fanfiction, there could be the idea of Luffy sharing his Gear 5 power with his crewmates temporarily. This would not only make for some cool team - up attacks but also show the deep bond within the Straw Hat crew. Also, a fanfiction might explore how Luffy's Gear 5 affects his relationship with other pirates or the World Government. Maybe it makes him an even bigger target or maybe it causes some pirates to want to ally with him out of fear or respect.
They might be shocked. Luffy's Gear 5 is such a powerful and strange form. In the fanfiction, characters could be amazed at his new abilities, like his cartoon - like movements and seemingly limitless power.
Well, it's still unknown if Luffy has found the One Piece. The manga is ongoing, and fans are eagerly awaiting to see if and when he reaches that ultimate goal.