Yes. The success of Spider-Man in the MCU has prompted the release of comics that either complement or expand on the events and characters seen on the big screen.
The relationship between Spider - Man and Natasha needs to be believable. It can't be forced. If it's a friendship, it should grow gradually through shared experiences. If it's more of a mentorship, there should be clear moments of learning and growth for Spider - Man. Also, the writing style should be engaging, with vivid descriptions of the action scenes and the characters' emotions.
The main event is the spider bite. It's what starts it all. Then there's the realization of his powers. Another important event is the death of his Uncle Ben which shapes his moral code. And finally, his first attempts at being a hero in his neighborhood.
One possibility could be that Spider - Man looks up to Natasha as a mentor figure. He's new to the world of the Avengers and Natasha, with her espionage skills and combat experience, could teach him how to better assess threats. For example, she could show him how to gather intelligence before jumping into a fight. They might go on a mission together where Spider - Man's quick thinking and Natasha's strategic mind combine to take down a powerful enemy.
If Spider - Man travels back in time, it could strengthen his relationship with Uncle Ben. He might get a chance to really talk to him and understand his values better, which would in turn make him a better hero in his own time. Also, his relationships with his friends like Ned and MJ could be affected. For example, if he changes something in the past, he might come back to a different present where their relationships have shifted.
In the fanfiction, their relationship could be a complex one. At first, Spider - Man would be disgusted by Venom's appearance and his violent tendencies. But Venom could be intrigued by Spider - Man's sense of justice. As time goes on, they could start to learn from each other. Spider - Man could teach Venom about restraint, and Venom could show Spider - Man how to be more assertive in a fight.
In the fanfiction where MCU Spider - Man and Venom meet, Spider - Man might initially be terrified of Venom. After all, Venom is this big, hulking, and somewhat menacing figure. However, as the story progresses, they could start to understand each other. Venom could realize that Spider - Man isn't just some weakling, and Spider - Man could see that Venom has his own motives that might not be entirely evil. They might then form an uneasy alliance.
One idea could be that Spider - Man travels back in time to the moment when Uncle Ben was killed. He tries to prevent it, but realizes that changing this event would have unforeseen and disastrous consequences for the future. So, he has to watch it happen again, but this time he gains a new perspective on his powers and responsibilities.