In 'deku meets future deku fanfiction', perhaps the future Deku warns the present one about upcoming threats. He could tell him about villains he'll face in the future and how to defeat them. This would give the present Deku an edge in his battles and also in his growth as a hero.
Well, obviously Deku in two forms - the younger and the older version are the main characters. The younger Deku is the one who is still growing and learning, while the older Deku has more experience.
One possible plot could be that Villain Deku is on a mission to undermine the hero society and crosses paths with Hero Deku. They engage in a fierce battle where Villain Deku taunts Hero Deku about his ideals. In the end, Hero Deku manages to get through to a small part of Villain Deku's conscience, leaving him with some doubts about his villainous path.
Another possibility is that a new villain emerges as a result of the time - travel or whatever mechanism brings future Deku to the present. This villain could be from a future where Deku's actions (or inactions) have led to a more dangerous world, and he travels back in time to stop Deku from making those mistakes again. However, his methods are extreme and dangerous, making him the antagonist of the story.
Another plot might involve the older Deku being from an alternate timeline. He shows the younger Deku different ways he could have developed his skills and relationships, which makes the younger Deku reevaluate his own path as a hero.
Villain Deku might start to question his villainous ways. Meeting Hero Deku could make him see the good in heroism. Hero Deku, on the other hand, could become more empathetic towards those who turn to villainy. He might realize that there are reasons behind it and not all villains are just 'evil' for the sake of it.
A possible plot is that Villain Deku has a plan to destroy a major hero institution, and Hero Deku has to stop him. But when they meet, Hero Deku realizes that Villain Deku was once like him, full of hope. This makes Hero Deku hesitant to fight at full force. Or perhaps Villain Deku has kidnapped someone close to Hero Deku, and during the rescue mission, Hero Deku tries to convince Villain Deku to change his ways. Also, they could be from alternate universes where the roles are reversed, and they are forced to interact and learn from each other.
For Hero Deku, his development could be shown by how he reacts to seeing his dark self. He might start to question his own beliefs and actions. For Villain Deku, his development could be in the form of a possible redemption arc. Maybe he starts to see the error of his ways through his interactions with Hero Deku. For example, if Hero Deku shows him kindness or understanding that he never received before.
I think Uraraka would be very excited. She has always been a big supporter of Deku. Meeting Future Deku would give her a chance to see how far he has come, and she might also get some inspiration for her own hero journey. Plus, she's a friendly and emotional character, so she'd likely be thrilled at the opportunity.
One common theme is friendship. Their meeting often focuses on how they support and encourage each other. Another theme could be growth, both in terms of their quirk development and personal growth.