Katara could be one of the main characters. She might play a role in helping Aang through the process of opening his chakras, either with her healing abilities or just by being there to support him emotionally.
The fanfiction might focus on how opening his chakras changes Aang's relationship with his friends and his role as the Avatar. For example, it could make his connection with the spiritual world stronger, leading to new abilities that he has to learn to control. It could also explore how his friends react to this new, more powerful Aang.
Yes, if the title 'aang is a firebender fanfic' is to be taken literally, then aang is likely a firebender within this fanfic. However, without actually reading the fanfic, there could be some sort of plot twist or alternative interpretation that might make it not so straightforward.
Since 'lemon' fanfic is inappropriate, we can't really discuss the characteristics in that context. But in general, aang is known for his kind - hearted and adventurous spirit. Toph is strong - willed and independent. In proper fanfic, these traits are often explored in their relationship, like how aang's optimism might contrast with toph's more cynical view at times.
He could meet his future self. It would be an interesting encounter as he could learn from his future experiences and wisdom. Or he might meet people who have studied his past adventures and see himself through their eyes.
Possibly they are random villagers who were caught in the crossfire of a conflict between different bending factions. Aang, being the Avatar and a symbol of peace, feels responsible for burying them and ensuring their spirits are at peace.
He might start by observing. Aang is a curious person, so he'd likely watch how people live, how they interact with technology. He may also try to find other benders to learn about any new developments in bending. And he'd probably use his kind heart to make friends easily in this new future environment.
Sokka could be one of the main characters. He might be the one helping Aang with his schoolwork, especially in subjects like history or math, using his own knowledge and quick thinking.
Aang might go into a deep state of depression. He has always been an emotional character, and having his heart broken by Katara, someone he loves deeply, could send him into a downward spiral. He might isolate himself from his friends and stop practicing his bending for a while.