In a 'kokushibo meets tanjiro fanfiction', one possibility is that Kokushibo senses something different about Tanjiro right away. Maybe it's the fact that Tanjiro has a unique scent or an energy that Kokushibo has never encountered before. Tanjiro, being Tanjiro, would be ready to face Kokushibo head - on, but also be open to communication if there's a chance. The story could explore their different views on the world of demons and slayers, and how they might come to understand each other better through their encounter.
Toge Inumaki is important too. His special cursed speech ability makes him stand out. Also, the principal of the school, Masamichi Yaga, is likely to be important as he is in a position of authority and has an influence on Gojo and the other students. There could be other characters like the members of different clans that also play roles in the complex web of the story.
For Tanjiro, he could become more understanding of the complex nature of demons. Meeting Kokushibo, a powerful and complex demon, might make him realize that not all demons are simply evil. Kokushibo, on the other hand, could start to have some doubts about his loyalty to Muzan. Tanjiro's tenacity and belief in the good of all might start to chip away at Kokushibo's cold - hearted exterior.
The battle of Yoriichi vs Kokushibo can be found in the advanced stages of the Demon Slayer manga. It's an intense and highly anticipated confrontation. The build-up and action are both masterfully depicted.