It really depends on how you write it. If it's Anakin at his peak before turning to the dark side, he has a lot of raw power and potential. But Vader has years of experience as a Sith Lord. So, it could go either way.
Luke Skywalker could be another key character. Since he is Vader's son, his presence could add an interesting dynamic. He might be the one who somehow triggers the battle between Anakin and Vader, or he could be in a position to influence the outcome of their fight, perhaps by appealing to the remaining good in Anakin or by facing off against Vader himself in a three - way struggle.
One idea could be a what - if scenario where Anakin in his pre - Vader state somehow gets a glimpse of his future as Vader. He could then fight against the dark side within himself that would turn him into Vader. Another could be a time - travel plot where Vader is sent back to face Anakin, and Anakin has to decide whether to accept his possible future or fight against it.
A fan fiction could also explore a parallel universe where Anakin and Darth Vader are two separate entities that co - exist. They are forced to fight not because of Anakin's fall, but due to some external force that wants to see the two most powerful Sith - like beings battle it out. This could lead to an exploration of their different fighting styles and the power dynamics between them.
In such a fanfic, the Avengers' diverse powers would clash with Darth Vader's formidable Force abilities. Iron Man could use his high - tech suits to try and outmaneuver Vader's lightsaber attacks. Captain America might lead the charge with his shield against Vader's dark side - enhanced combat skills. It would be an epic battle of good from different universes against Vader's Sith - influenced evil.
One idea could be a story that focuses on Anakin's internal struggle between his love for Padme and his fall to the dark side as Darth Vader, while Luke and Leia unknowingly grow up in the shadow of their father's actions. It could explore how their lives might have been different if Anakin had not turned, and how they eventually come to terms with his true identity.
Well, obviously Anakin and Vader are the main characters. Anakin is his pre - Darth Vader self, full of potential and hope at one point, and Vader is the dark, powerful Sith Lord he becomes.
One interesting plotline could be Anakin's struggle with his past self as Vader. Maybe in the fanfic, Anakin tries to prevent Vader from making the same mistakes he did, leading to intense battles of will and lightsaber duels.
A possible plot is a fanfic where Anakin, in his Darth Vader form, has a vision of a different future where he didn't lose Padme. This vision makes him question his loyalty to the dark side. Meanwhile, Luke and Leia are on a mission to rescue their father from the clutches of the Emperor. The story could be filled with emotional reunions and battles between the light and dark forces.