You can try completing certain quests or participating in specific events related to it. Sometimes, rare drops from monsters might also give you a chance to obtain it.
One good order could be starting with the Tutorial Island quests as they introduce the basic mechanics. Then move on to the Lumbridge quests which are relatively easy and build a foundation. After that, quests like the Vampire Slayer quest can be a good next step as it has an interesting story and unlocks some useful items and areas.
One possible plot could be Percy discovers he has a special connection to the Hellhounds. Maybe he is able to communicate with them in a way no one else can. He then has to use this ability to solve a mystery in the demigod world. For example, some important items have been stolen and the Hellhounds know where they are, but they will only tell Percy.
A powerful Titan who wants to use the Hellhounds for his own evil purposes could be the main antagonist. He might try to capture Percy and force him to command the Hellhounds to do his bidding, like attacking the demigod camps.
For a new player, start with the basic beginner quests like the Imp Catcher. It's easy and gives a feel for how quests work. Then, try the Witch's Potion quest which is also simple but starts to introduce more of the game's world. After that, the Dragon Slayer quest is a big step, but it has a great story and is a classic in the OSRS quest line.
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