Definitely. Sabrina the Teenage Witch started as a comic and later expanded into different entertainment mediums. The comic introduced the beloved character and her magical adventures to the world.
Definitely not. Sabrina the Teenage Witch has no connection to Marvel Comics. It has its own independent comic book origin and publication history outside of the Marvel universe.
One possible fanfiction idea could be that Sabrina gets hurt while trying to protect her friends from a dark magic spell gone wrong. Maybe she takes on too much of the spell's backlash and ends up with some magical burns or a weakened state. Her friends then have to figure out how to heal her and reverse the spell's effects.
Sabrina herself is a main character. She's a teenage witch with all kinds of magical powers. Her aunts, Hilda and Zelda, are also important. They are more experienced witches and often guide Sabrina. Salem, the talking cat, is another key character. He's usually there to offer his own brand of advice, which is sometimes helpful and sometimes not so much.
The main character is Sabrina herself. Then there are her two aunts, Hilda and Zelda. And Salem, the talking cat. These are the most prominent characters in the original story.
One of the top stories could be Sabrina's struggle to balance her magical life with her normal high - school life. For example, she has to deal with typical teenage problems like dating and schoolwork while also handling her witchy powers and the magical world's rules.
A fanfiction could focus on Salem's backstory. What if he was once a great wizard in his own right but was cursed to be a cat? Sabrina could discover this through a magical accident and try to find a way to break the curse. This could lead to adventures in different magical realms as they search for the solution.