Spider-Man has definitely been in the Avengers in the comics. His presence has added a fresh dynamic and his powers and wit have been valuable assets to the group.
One interesting storyline could be Spider - Man teaming up with the Avengers to fight a new super - villain that's a combination of different powers they've faced before. For example, a villain with the strength of the Hulk and the mind - control abilities of Loki.
Well, maybe he's got some secret mission that he doesn't want the Avengers to interfere with. You know, like protecting a particular person or some crucial information that he thinks the Avengers might mess up if they get involved.
Another possibility is that the Avengers are being manipulated by a villain. The bad guy could be using false information to make the Avengers believe that Spider - Man is a danger. So they go after him without really knowing the truth.
Spider - Man would likely be confused at first. He respects the Avengers and can't understand why they are suddenly after him. He might try to talk to them, to explain that he's innocent. For example, he could swing up to Captain America and start pleading his case.
Spider - Man would probably be shocked at first. He looks up to the Avengers and being kidnapped by them would be the last thing he expects. He'd likely try to talk his way out, using his quick wit and charm. He might start by asking why they're doing this and try to convince them that they've made a mistake.
Spider - Man would be very confused. He would feel betrayed because he thought the Avengers were heroes he could trust. He could start by asking them why they are doing this. If they don't give him a satisfactory answer, he might try to escape in a sneaky way, using his spider - like abilities to find a weakness in their capture setup while still trying to reason with them.