With Robin, focus on her past and how it shapes her reactions to the OC. Her trauma from Ohara can make her initially guarded. But as the story progresses, the OC's presence can help her open up more. For Nami, emphasize her love for money and the crew. The OC can either support her in her money - making schemes or challenge her views, which develops her character further.
For the OC, give them a distinct personality trait. For example, if they are overly curious, it can lead to interesting interactions with Robin's love for knowledge and Nami's practicality. Show their growth over time, like learning from Robin's wisdom and Nami's street - smart ways.