A new, young ninja from a minor village could be the main character. They could be trying to make a name for themselves and their village at the Kage Summit. They might get involved in some political intrigue or even a fight between the Kages and prove their worth.
It could be Naruto himself. Since he has a connection to all the villages in some way, he could play a crucial role in the fanfic, perhaps as a mediator or someone who uncovers a hidden conspiracy during the summit.
Naruto could still be the main character. As the Hokage, he would be at the center of the Kage Summit. His ideals of peace and unity would play a major role in the interactions with the other Kages. He might try to convince the other Kages to support a new initiative for a more united ninja world.
It could be a rogue ninja who has a vendetta against all the villages represented at the summit. He might have been wronged in the past by the combined actions of the five great villages and now seeks revenge. He could use the chaos of the summit to launch attacks and try to undermine the stability of the shinobi world.
A young and inexperienced ninja from a small village could be the main character. He could be sent to the Gokage Summit as an observer or a messenger. Through his eyes, the readers could experience the grandeur and the political complexity of the summit.
Naruto himself could still be the main character, but this time showing even more advanced kage - level skills. Maybe he's facing a threat that only his new and improved abilities can handle.
The Kages themselves are often main characters. For example, Tsunade from Konoha, Gaara from Suna, and the other village leaders. They play important roles in the political and power - related discussions during the summit.
Perhaps in the fanfic, a young shinobi manages to infiltrate the Five Kage Summit and has a significant impact on the discussions. This shinobi could bring new ideas or warnings that change the course of the kages' decisions. For example, he might have uncovered a plot by a rogue ninja group to take advantage of the kages being gathered in one place. This would not only create tension between the kages and the external threat but also among the kages themselves as they debate how to handle this unexpected situation.
In the fanfic, Naruto being cold after the Kage Summit could lead to some interesting character developments. His friends might be worried about him and this could strengthen their bonds. Also, it could be a sign of some sort of new power or curse that he got during the Summit, which would then drive the plot forward as they try to figure out what's wrong with him.
Other villages' leaders or powerful ninjas who don't believe Naruto is ready to be a Kage. They might try to test him or even plot against him during diplomatic meetings before the summit, seeing his new position as a potential weakness in the balance of power.
Sasuke could be one to stop Naruto. They have a complex relationship and Sasuke might understand Naruto's motives and be able to talk him down.