Madara Uchiha would be a formidable foe. His Sharingan abilities are second to none and his experience in battle is vast. He could easily outwit and overpower the team with his powerful jutsu and strategic mind. Plus, his connection to the Uchiha clan's history gives him an edge in understanding and countering the team's moves.
It could be Sasuke. Sasuke is highly intelligent and has a great strategic mind. He would approach shogi with the same intensity as he does his ninja battles. He would be able to analyze Naruto's moves quickly and counter them effectively.
Madara Uchiha. He is extremely powerful with his Sharingan and Rinnegan abilities. Even if Naruto is a martial arts master, Madara's vast array of jutsu and his strategic mind would make him a formidable foe. He could use his space - time ninjutsu to avoid Naruto's attacks and then counter with powerful attacks of his own.
I think Gaara could be a really tough opponent for Naruto in an MMA - like scenario. Gaara has great control over his sand, which could be used defensively and offensively in a fight. He's also very resilient and has a lot of experience in combat. His stoic nature would make it difficult for Naruto to read his moves and find an opening. And Gaara's determination to win is on par with Naruto's.
Jiren could still be a tough opponent in the 'vegito tournament of power fanfiction'. His power level is extremely high, and he has great combat skills. Even for Vegito, defeating Jiren would be no easy feat as Jiren has proven his strength time and again in the original tournament.
Loki would also be a difficult adversary. He's very cunning and could use his tricks and illusions to try and outwit Goku. Goku would need to rely on his senses and ki to see through Loki's deceptions.
It could be Alain. Alain is a very strong trainer in the Kalos region. He has a powerful team and his bond with his Charizard is quite strong. If Ash has to win the Kalos League, facing Alain would be a huge challenge as Alain has a lot of experience and his battling skills are top - notch.
It could be a new character created specifically for the fanfiction. A trainer with some super - rare and powerful Pokémon that Ash has never faced before. This trainer might have unique battle tactics that really test Ash's skills.
His toughest opponent could be Gary. Gary has always been a rival to Ash and has a strong and diverse team of Pokemon. Their battle would be intense as they both know each other's battling styles well.
It might be another new and mysterious trainer in the Kalos league. This trainer could have some rare and never - before - seen Pokémon with unique abilities. But Ash, through his experience and the growth of his Pokémon over time, is able to find the weaknesses of these new Pokémon and defeat this tough opponent. His ability to adapt to different battle situations and his Pokémon's loyalty are what make him victorious.
Sasuke could still be a tough opponent. Even though Naruto has all elemental affinities, Sasuke has his own powerful Sharingan and Rinnegan abilities. He can manipulate Amaterasu and other powerful techniques. Their rivalry would be intense as Naruto tries to use his newfound elemental powers against Sasuke's ocular powers.