It could be Darth Sidious. He is always looking for powerful allies. If he senses Ahsoka's potential and her growing disillusionment with the Jedi, he might manipulate her into joining the Dark Side. His cunning and power would make him a formidable antagonist in this scenario.
The Jedi Council themselves could be seen as antagonists in a sense. If they are portrayed as overly strict, dogmatic, and unsympathetic towards Ahsoka, it could fuel her anger and resentment. Their actions, like exiling her or not believing her when she's innocent, could be what drives her to consider the Dark Side as an alternative. So, in this case, the Council's rigidity and lack of understanding would be the antagonistic force.
She could be driven by a sense of betrayal. Maybe she discovers that the Jedi Order has been hiding something crucial from her, like a dark secret about her past or a false promise they made. This could shatter her trust in the light side and make her vulnerable to the temptations of the Dark Side.
Palpatine could still be the main antagonist even if Luke turns to the dark side. He might try to use Luke as a more powerful weapon against any remaining Jedi or the Rebel Alliance. Palpatine would see Luke's newfound dark side power as a means to further his own control over the galaxy.
Ahsoka might be exiled from the Jedi Order for reasons she doesn't fully understand. In her solitude, she meets a mysterious figure who has ties to the Dark Side. This figure begins to teach her alternative ways of using the Force that are more in line with the Dark Side. Ahsoka, feeling betrayed by the Jedi, starts to consider these new teachings.
One possible story could be that Ahsoka, after facing a series of great losses and betrayals, starts to be tempted by the Dark Side. Maybe she discovers some ancient Sith knowledge that makes her question her Jedi teachings. She could struggle with the newfound power it offers and the darker emotions it stirs within her, like anger and vengeance.
One possibility in fanfiction could be that Ahsoka is tricked into the Dark Side. Maybe an old enemy manipulates events to make her feel betrayed by the Jedi Order. This could lead her to explore the power of the Dark Side, believing it to be a way to seek justice on her own terms.
Perhaps a group of dark side cultists could be the main antagonists. They idolize the power of the dark side and see Ahsoka as a prime candidate to join their ranks. When she refuses at first, they start to hunt her down, but in the process, they unknowingly push her closer to the dark side, creating a complex dynamic where they are both the pursuers and the inadvertent cause of her fall to the dark side.
It could be an existing villain from the original story who sees Adrien's potential and manipulates him into turning to the dark side. For example, a powerful sorcerer or a mastermind criminal. They could use Adrien's weaknesses, like his desire for power or his need to prove himself, against him.
The influence of a powerful dark side user who targeted her specifically. This user could manipulate her emotions, play on her insecurities and gradually turn her towards the dark side. They might offer her knowledge or power that she couldn't resist, slowly corrupting her view of the Force.
She might be tempted by the Dark Side if she discovers a hidden truth about the Jedi Order that she can't accept. So she turns to the Dark Side thinking it's a better alternative. For instance, if she finds out that the Jedi have been hiding some dark secrets about the Force, it could push her over the edge.
It could be Sasuke. If Sasuke continues to pursue his own vendetta in a more extreme way and Naruto's attempts to bring him back fail, Sasuke could become the main antagonist. Their rivalry could turn into a full - blown battle for power and ideology, with Naruto being pushed to his limits and potentially turning dark in the process of trying to stop Sasuke.