A more complex plot could be set in a world where there is a threat to all Pokemon. Ash and Astrid, along with their Pokemon friends, have to gather a set of ancient artifacts to save the Pokemon world. Along the journey, they have to overcome their own personal doubts and differences to succeed.
One idea could be that Ash and Maya embark on a journey to find a rare and powerful Pokemon that is said to be able to control the weather. Along the way, they face challenges from a team of villains who also want the Pokemon for their own evil purposes.
One interesting plot idea could be Ash getting lost in Sabrina's psychic maze and having to rely on his Pokémon's instincts more than his own. Another could be Sabrina having a premonition about Ash's future battles and deciding to train him in psychic - type moves. Or perhaps there's a Pokémon that is causing chaos in the town and Sabrina and Ash have to team up to stop it, which also helps Sabrina to open up more and become less aloof.
One interesting plot idea could be Ash and Dawn teaming up to explore a new, uncharted region in the Pokemon world. They could encounter rare and unique Pokemon species that are not known to the rest of the world. Another idea is that they participate in a special tournament where the rules are very different from the regular Pokemon battles, like battles on floating platforms or with certain type restrictions. A third plot could be that they discover a mystery related to an ancient Pokemon civilization and have to solve it to save the present - day Pokemon world from some kind of threat.
One idea could be that Ash and Latias team up to save a group of Pokémon from an evil organization. Ash uses his battle skills and Latias uses her psychic powers.
One idea could be that Ash and Manaphy go on a journey to find a rare type of Pokemon food that can heal all Pokemon. Another could be that Manaphy gets lost and Ash has to traverse through a dangerous forest to find it. Or perhaps they team up to save a group of Pokemon from an evil trainer.
One plot idea could be Ash and Red teaming up to face a new, extremely powerful and mysterious Pokemon. They would have to combine their unique skills and knowledge of different Pokemon regions.
Maybe Ash and his Pokemon travel to a parallel dimension where the rules of Pokemon battles are completely different. In this dimension, Pokemon can combine their powers in unexpected ways. Ash has to quickly adapt and learn these new battle styles in order to compete in a grand tournament there and find a way back to his own dimension.
Maybe a fanfic where Ash and Brock discover a hidden Pokemon village that is in danger from a powerful, evil Pokemon. They must use their skills and the help of the village Pokemon to defeat the threat. This could involve Brock using his knowledge of Pokemon care to heal the injured village Pokemon, while Ash strategizes for the battle.
One idea could be Ash and Sabrina teaming up to face a new and powerful Pokemon that threatens their region. They have to combine their unique skills and knowledge of Pokemon to defeat it.
Well, the plot could involve Ash's unique starter being from a far - off region that was thought to be extinct. This starter could hold the key to an ancient mystery in the Pokemon world. As Ash travels with it, they encounter various challenges related to protecting this starter from those who would use its uniqueness for evil purposes. The starter might also have an ability to transform into different forms depending on the situation, like a more powerful form when facing a tough opponent.