Well, in fanfiction where Natsu leaves the guild, he could become a sort of lone wolf. He might travel to far - off lands to discover more about his dragon - slayer powers or his past. This could lead to him meeting new and powerful allies or enemies. Without the support of the guild, he would have to rely solely on his own strength and wits. It could also make him a more serious and hardened character, as he no longer has the safety net of his Fairy Tail family.
One possibility could be that Natsu is under some sort of dark magic influence. Maybe a powerful enemy has managed to control his mind, making him turn against the guild master. Another reason could be a misunderstanding. If some false information is fed to Natsu about the guild master being a threat to the guild or his friends, his hot - headed nature might lead him to take drastic action without fully understanding the situation.
One possible plot could be that Natsu and Erza leave Fairy Tail due to some kind of internal conflict within the guild. Maybe there are differences in opinions regarding how the guild should be run or what kind of jobs they should take. So they decide to set out on their own journey to find a new purpose.
Natsu could end up teaming up with some unexpected allies from Tartaros. Maybe there are some members who have a change of heart and decide to help Natsu fight against the more evil elements within their own organization.
She could be a key figure in an ancient prophecy. For example, the prophecy might state that only the son of a certain dragon - slayer mother (Natsu's mother) would be able to defeat a great evil that threatens the Fairy Tail world. This would set Natsu on a path to discover his mother's identity and fulfill the prophecy.
Well, one possibility could be that Natsu leaves the guild because of a personal mission. Maybe he discovers a dark secret about his past that he believes can only be solved alone, so he leaves Fairy Tail to find out the truth without putting his friends in danger.
It could be that Natsu has some sort of falling - out with the members of Fairy Tail. Perhaps there was a misunderstanding during a big mission, and he decides he can't stay any longer. For example, if his actions were misinterpreted and the guild members blamed him for something that wasn't his fault. He might leave to prove his innocence elsewhere.
Gray would be shocked at first. He and Natsu have a long - standing rivalry - but also a deep friendship. He might initially be angry that Natsu would just leave like that, but then he would realize how much he'll miss him. He might also feel a sense of loss for the guild as a whole, since Natsu is such an important part of it.
Natsu could also be deeply hurt. He values his friends highly in Fairy Tail. If betrayed, he might isolate himself, doubting his own judgment in trusting people. This could lead to a period of self - discovery where he tries to figure out how to trust again. For example, he might recall the times when his friends in Fairy Tail were truly there for him and use those memories to heal and grow stronger in the face of this betrayal.
In such a fanfiction, Natsu might have become much stronger. Maybe he has mastered new fire - based magic techniques. He could also have new relationships within the guild, like closer friendships or even a romantic interest.
Natsu could bring a more fiery and passionate leadership style. He'd probably be more action - oriented than the previous masters. For example, if there's a conflict with another guild, he'd be the first one to charge into battle, leading by example.