Obviously, Percy Jackson himself is a main character. He's the one with the new identity as the son of Hades. Nico di Angelo could also be a major character as he has a strong connection to Hades already. And Annabeth Chase would likely be involved too, as she's Percy's close friend and often by his side in adventures. There could also be some new characters created specifically for the fanfiction, like a powerful Underworld spirit that becomes Percy's guide or an enemy within the Hades - influenced areas.
The main character is Percy. But in this fanfiction, characters like Hades himself might play a more prominent role than in the original series. He could be mentoring Percy in some ways or setting tasks for him. Another important character could be a demigod from a different cabin who initially distrusts Percy because of his new heritage but later becomes his ally. And of course, Grover could be there, providing his usual support and comic relief while also being involved in Percy's Underworld - related adventures.
The main characters are Percy and Fem Hades. Percy is the protagonist from the original series, and in the fanfiction, his story continues with his interactions with Fem Hades. Fem Hades, on the other hand, is a unique take on the Hades character. She could have different personality traits compared to the male Hades in the original mythology. There might be other characters that are introduced as the story progresses, but these two are the foundation of most Percy Jackson and Fem Hades fanfiction.
Well, there could be new demigod children of Hades. Maybe a girl who has the power to control the shadows in a unique way, like she can use them to create portals to different parts of the underworld. Or a boy who can communicate with the dead in a more advanced way than the usual children of Hades, and he has some sort of prophecy related to Percy.
Some of the more malevolent spirits or monsters from the Underworld could also be antagonists. They might resent Percy for being Hades' adopted son and try to undermine him. For example, a powerful undead general who believes he should be the one favored by Hades instead of Percy.
Annabeth Chase might also be an ally. Her intelligence and strategic thinking could be valuable assets for the son of Hades. She could help him plan his moves, especially when dealing with the complex politics among the demigods and gods.
One interesting plot could be Percy having to navigate the Underworld politics due to his relation to Hades. Maybe he has to deal with rivalries among the different factions down there while also trying to keep his identity a secret from some of the more dangerous entities. Another plot might involve him using his unique powers, a combination of Poseidon and Hades' abilities, to defeat a new and powerful monster that is threatening both the mortal and the underworld realms.
The main antagonist could also be an ancient and powerful spirit from the underworld that was sealed away long ago. Percy's presence as the son of Hades accidentally awakens this spirit. The spirit then starts to spread darkness and despair throughout the world of the demigods, and Percy has to find a way to stop it before it's too late.
Another option could be some rogue demigods who are jealous of the son of Hades' powers. They might form a group and try to cause trouble for him and Percy Jackson. They could be working with some minor gods who have a grudge against Hades, creating a complex web of enemies.
One idea could be Percy having to mediate between Zeus and Hades during a major feud. Since he's the son of both in this fanfiction, he has a unique connection to them. He could use his powers and his knowledge of both of their domains to try and broker peace.
The main character is Percy Jackson. Alongside him, we may have some characters that are exclusive to the fanfiction world. For example, there could be a character who is a half - human half - stone being as a result of Medusa's powers in the past. This character could be an ally or an enemy to Percy. Then there's a good chance that Chiron, the centaur trainer at Camp Half - Blood, will be in the story. He's always been a guiding figure for Percy, and in this new context, he'll have to give Percy advice on how to handle his new identity as the 'Son of Medusa'.
Obviously, Percy Jackson is one of the main characters. He's the central figure around which the story usually revolves.