Iron Man is a great character to pair with Spider - Man. Tony Stark can act as a mentor to Peter Parker, providing him with new and advanced tech for his suit. They also have a fun dynamic, with Stark's sarcasm and Spider - Man's youthful exuberance.
Black Widow can also be an interesting pairing. She can train Spider - Man in combat skills and espionage. Her stealth and combat expertise combined with Spider - Man's super - powers would make for some really cool and sneaky mission scenarios in the fanfic.
Daredevil could also be an interesting pairing. Both are street - level heroes with enhanced senses in a way. Assassin Spider - Man's acrobatic and stealth skills combined with Daredevil's martial arts and heightened senses would make for an exciting story. They could work together to clean up the seedy parts of the city.
Captain America is another good option. Steve Rogers' sense of justice and leadership could influence Spider - Man in a positive way. And the contrast between the old - fashioned Cap and the young, modern Spider - Man would create some great story dynamics.
One interesting storyline could be Spider - Man teaming up with the Avengers to fight a new super - villain that's a combination of different powers they've faced before. For example, a villain with the strength of the Hulk and the mind - control abilities of Loki.
Black Cat is a great choice. Her cat - like agility and thieving skills would blend well with Spider - Man's acrobatics and sense of justice. Their relationship in the comics already has a lot of potential for a hybrid - style fanfiction where they combine their skills in new ways.
Spider - Man and Iron Man are really popular. They have a mentor - mentee kind of relationship in many fanfictions. Iron Man can offer his technological expertise to Spider - Man, and Spider - Man can bring his fresh perspective and street - level heroism to the table.
Peter Parker (Spider - Man) and Robin would make a great pair. They are both intelligent and resourceful, and their different fighting styles would complement each other well. Robin's detective skills combined with Spider - Man's spider - sense could lead to some amazing crime - solving adventures.
Artemis could be a great pairing. She's a skilled archer and a strong - willed character. Spider - Man and Artemis could have some great banter while on a mission, and their combined skills would make them a formidable duo.
Peter Parker (Spider - Man) and Captain America are also quite popular. You can see stories where Captain America takes Spider - Man under his wing, teaching him about heroism and leadership. It's an interesting dynamic as they come from different generations of heroes.
Some fanfics explore the Superior Spider - Man's relationship with the other superheroes. They might not trust him at first because he's not the same as Peter Parker. So, the plot could revolve around him trying to prove himself to the Avengers or other heroes in the Marvel universe. This often leads to some tense and exciting interactions.
The Avengers would be very concerned. Captain America would immediately take charge of the situation, trying to keep everyone calm while they assess Spider - Man's injuries. Iron Man would start scanning for the best way to treat him, using his high - tech equipment. Thor might offer some of his Asgardian knowledge of healing, if there was any. Black Widow and Hawkeye would be on guard, making sure there were no further threats while the team focused on Spider - Man.