Thor would be one of the active ones. He has a lot to share from his Asgardian experiences. Hulk, well, he might not type much but when he does, it would be in short, powerful statements. And Scarlet Witch could be in there too. She could use her powers to sense if there's any danger approaching the chatroom or the Avengers themselves while chatting with the others.
Obviously, the main Avengers like Iron Man, Captain America, Thor, Hulk, Black Widow, and Hawkeye would be the main characters. They are the core of the team and any story about the Avengers, drunk or not, would likely center around them.
The plot might involve a new villain who hacks into their chatroom. So, the Avengers have to figure out how to stop this digital threat while also communicating within the chatroom to coordinate their efforts. They could be discussing their individual strengths and how to use them against this new enemy. For example, Captain America could be leading the conversation on strategy, while Black Widow provides intel she's gathered. Hulk might be there just being Hulk, with the others trying to keep him calm and on track. And all of this happening in the unique setting of a chatroom, which adds a modern and interesting twist to the typical Avengers story.
Captain America is very likely to be featured. He has that paternal, moral - compass kind of vibe. He would be the one to gently tickle the 'daughter' as a way of showing his soft side. Thor could also be a popular choice. His big - hearted and sometimes child - like nature would make for some great tickle - related antics with the 'daughter' figure.
Captain America could be a likely character to be betrayed. He represents the old - school values of the Avengers, and in a more modern, cynical world within fanfiction, some might see his ideals as outdated and turn against him. Also, Tony Stark. His wealth and sometimes over - confident attitude could make some of the other Avengers, especially those with more humble backgrounds, feel resentful and potentially betray him. And Thor, being an Asgardian, might be betrayed due to the other Avengers' mistrust of his alien nature or the potential threat Asgard could pose.
Captain America and Peter would also have great interactions. Steve Rogers could teach Peter about the importance of responsibility and leadership. And Peter, with his youthful enthusiasm, could remind Steve of the good in the world and the future.
Tony Stark could also be a key figure in some fanfics, even though he's no longer alive in the main MCU timeline. His intellect and previous experiences with multiversal - related events (like in Endgame) could be explored in the fanfic. Maybe the Avengers find a way to access his knowledge or even a version of him from another universe to help them out.
Tony Stark is a likely focus. His intelligence and experience with technology, especially time - travel technology in the movies, make him a central figure. He could be the one to figure out the mechanics of time travel and lead the Avengers in their time - traveling adventures.
Death from DarkSiders and Black Widow could have an interesting interaction. Death has seen countless deaths and has a very different perspective on life and death compared to the human Black Widow. Their conversations could be deep and thought - provoking as they work together on a mission.
Tony Stark is likely to be a focus. His flamboyant and playboy - like personality could lead to some really interesting scenarios when affected by a love potion. He might make grand gestures towards someone he wouldn't normally be interested in. Another likely character is Natasha Romanoff. Her complex past and guarded nature could create a great contrast when the love potion breaks down her walls.
Captain America is a likely candidate. He has a strong moral compass and a sense of protectiveness. He would see it as his duty to take care of the baby. His old - fashioned values would make him a great caregiver, like making sure the baby has a proper upbringing even in the middle of all the chaos in the Avenger's world.