If it's set in a school or work environment, Bella's friends or colleagues could be main characters. They might notice the changes in Bella as she discovers this new family connection. Also, if there are antagonists in the story, it could be someone who doesn't want Bella and Billy to form a relationship. This could be someone who has a grudge against Billy and sees Bella as a way to get to him, or it could be someone who is jealous of Bella getting a new family.
Well, it could be the people she targets. They would be important as they drive the action when Bella is on her 'killer missions'.
The main characters are Bella, Charlie, and Billy. Bella is often portrayed as a curious and adventurous character. Charlie is usually seen as a reliable and protective figure, like a father. Billy has a certain wisdom and local knowledge that adds depth to the stories.
Edward could be one of the characters. He might be in a love - hate relationship with Bella due to her addiction. He could be torn between his love for her and his inability to stand her self - destructive behavior.
Foster parents are likely to be important characters. They could be kind and nurturing, or perhaps they have their own issues that create more drama for Bella.
There could be Klaus. Since he is Rebekah's brother, he would likely be part of Bella's life in some way. He might be a protective uncle or a source of conflict if he has different ideas about how Bella should be raised. Another character could be Elijah. He might act as a mentor to Bella, teaching her about their family's history and values.
Caroline could be in the story. She might be Bella's friend or a rival. If she's a friend, she could help Bella navigate the supernatural world. If a rival, it could be because of her relationship with Damon or Stefan in some way. Also, Klaus could be a character. He might see Bella as a means to get to Damon, or he could be interested in her unique abilities if she has any.
There could be Edward. Even if Bella is now immortal, Edward might still play a significant role. He could be either her eternal love or her adversary depending on how the fanfiction is written. Another character could be Alice. Since Alice has her own special abilities, she might be there to help Bella navigate the new world of immortality. For example, she could foresee some of the challenges that Bella will face. Also, Jacob might be a main character. His relationship with Bella, whether it's a friendship or something more complicated, could be further explored in the context of Bella's immortality.
There could be Edward. Maybe he is involved in Bella's life with her psychic powers. He might be curious about her abilities or even try to protect her from the consequences of using those powers.
The Cullens are very likely to be involved. Edward, of course, would have a huge role as Bella's former love interest. Carlisle, with his knowledge and experience as a vampire, could help Bella adjust to her new life. Alice might use her precognitive abilities to foresee any problems Bella could face. Also, Jacob could be in the story. His reaction to Bella becoming a vampire would be interesting, considering his past relationship with her and his werewolf nature.
One common theme is friendship. They often explore how Bella and Billy become friends and support each other. Another theme is discovery, like Bella discovering new aspects of Billy's life or vice versa.