Obviously, Ash is one of the main characters. He's the protagonist who has a passion for pokemon and is always eager to become a pokemon master. And the legendary pokemon he encounters or befriends would also be important characters. For instance, if it's Lugia, Lugia would play a major role in the story as it's a very powerful and mysterious pokemon.
His Pikachu would also be a key character. Pikachu has been with Ash from the start and would likely be involved in any adventures with the legendary pokemon. It could be that Pikachu helps Ash communicate with the legendary pokemon in some ways, or they team up to protect the legendary pokemon from danger. There might also be other friends of Ash, like Brock and Misty, who could support Ash in his interactions with the legendary pokemon.
The villains in the fanfiction could also be considered main characters in a sense. They might be after the legendary pokemon for their own evil purposes. Their actions would drive the conflict in the story and force Ash to take action to protect the legendary pokemon. So, characters like Team Rocket or any new evil teams created in the fanfiction would be important parts of the story.
Obviously, Ash is one of the main characters. Since it's about him being a legendary Pokemon in this fanfiction, he's central to the story.
Obviously, the Legendary Pokemon would be a main character. It could be a Pokemon like Mewtwo, who is often depicted as having a complex personality. It might start off as a mysterious and powerful entity that Ash has to befriend or battle against.
Obviously, Ash is one of the main characters. He is the trainer who gets the legendary starter. And of course, the legendary starter itself is also a main character. It has its own personality and abilities that play a big role in the story.
The villains in the fanfiction can also be considered main characters in a sense. They might be after the power of the legendary Pokemon. There could be a team of bad guys who are trying to capture and control a Groudon or a Kyogre to cause chaos in the Pokemon world, and Ash has to stop them. Their actions and plans create the conflict that Ash has to overcome in the story.
Articuno, Zapdos, and Moltres are quite common. Their elemental powers and the mystery surrounding them make for great fanfiction material. Ash might encounter them during his travels and have to either help them or face off against them in some way.
One of the Legendary Pokemon could be Giratina. Despite its somewhat dark and otherworldly nature, Giratina might be intrigued by Ash's light - heartedness and his ability to make friends with all kinds of Pokemon. Dialga and Palkia could also be part of the harem. Dialga, with its control over time, might see Ash as an important factor in the future of the Pokemon world. Palkia, in charge of space, could be interested in how Ash navigates different regions and spaces in his journey. And don't forget about Ho - Oh. Ho - Oh is a symbol of hope and might see Ash as a bringer of hope in the Pokemon world, thus joining his harem.
Arceus is quite popular. Given that it's considered the creator of the Pokemon universe in the official lore, it often has a significant role in fanfictions. Mewtwo is also very common. Its powerful psychic abilities and complex backstory make it a favorite for fanfic writers to explore. Another popular one is Lugia. With its majestic appearance and its connection to the sea, it's often a central figure in many stories.
It could be Mew. Mew is known for its ability to transform and has a very mysterious nature. If Ash was Mew's son, he might inherit some of that mystery and the power to communicate with Pokemon in unique ways.
In the fanfiction, perhaps there's a plot where Ash has to save a legendary pokemon from an evil organization. He might use his experience and the trust of his other pokemon to rescue it. This would not only show his courage but also how much he values all pokemon, whether they're common or legendary.
There are also fanfictions where Ash catches Rayquaza. This could be set during a time when the sky is in chaos due to some dark energy. Rayquaza is drawn to Ash because of his pure heart and determination. Ash, with his usual courage, teams up with his pokemon to assist Rayquaza in restoring balance. As a result, Rayquaza allows Ash to catch it.